• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    The invention provides an ensiling agent which contains, based on the total quantity of active ingredients, a mixture of from 50 to 90% by weight of salts of formic acid and from 10 to 50% by weight of hexamethylene tetramine or other compounds which slowly and continuously release formaldehyde during the fermentation of fodder plants.
    公开号:SU712008A3
    申请号:SU772444048
    申请日:1977-01-21
    公开日:1980-01-25
    发明作者:Бэкк Теодор；Гросс Фридрих
    申请人:Плате Кофазил Гмбх (Фирма)；
    IPC主号:
    专利说明:

    one
    The invention relates to the silage of fodder plants, especially difficult to ferment fodder plants.
    For the silage of difficult silage feeds (protein-rich green fodder), silage agents are used that improve the natural lactic fermentation and prevent the harmful effects of fermentation. The use of effective silage agents reduces feed loss due to nutrient breakdown.
    Plant silage agents are known that contain a mixture of nitrite and sestimethyl tetramine 1.
    The use of a mixture of nitrite and six-methyl tetramine does not always lead to a satisfactory result.
    The use of nitrite, especially at its relatively high concentration in a mixture of biologically active substances is dangerous, since animals and humans can be poisoned.
    Agents containing hexamethyltetramine and formic acid 2 are also known. When added to feeds at a calculated concentration, they often have only a small positive effect, and in many cases even have an adverse effect on fermentation.
    The aim of the invention is to increase the efficiency of the means for ensiling the plants, as well as improving its physical and mechanical properties.
    This is achieved by the fact that as a bacteriostatic agent, the agent contains calcium formate at the next component ratio, weight,%:
    Hexamethyltetramine 10-50 Calcium Formate 50-90 A method of ensiling forage plants is characterized by the fact that from 0.1 to 0.5% by weight of the above mixture is added to the ensiled product.,
    about the weight of green fodder, the content of six-methyl tetramine, which slowly and gradually cleaves formaldehyde from fodder plants during the fermentation process,
    5 does not have to exceed $ 0.1% by weight of green fodder.
    Calcium salt of formic acid (hereinafter referred to as formate) is added to the ferrous product.
    0 in an amount of from 0.05 to 0.5 wt.%. It is preferable to introduce Formate from 0.3 to 0.1% by weight. Accordingly, the amount of six-methyl tetramine (below HBT for short) should be from 0.01 to 0.1% by weight, since it was indicated above In no case shall the content of HMT exceed 0.1 wt.% of the weight of green fodder. Thus, if biocatalysts are used with a very high content of NMT, for example, at 50 wt. then the amount (in this example, 0.2 wt.%) of a mixture of biocatalysts should be added to the ferrous product, so that green feed contains the maximum amount of 0.1 wt.% HMT. Preferred is the administration of HMT from about 0.8 to about 0.02 wt.%. As a result of numerous experiments on siloing and microbiological research, it was found that using the proposed siloing means an extremely large synergistic effect of biocatalysts arises. The positive effect of Formates on the silo process, when used separately, occurs only at an extremely high, economically unprofitable concentration (at about 1 weight,% or higher). At. Using a preformed table of the invention for a mixture of formates and six-methyl tetramine, only a fraction of the usually required amount of formates is sufficient. For the specialist, the synergistic effect of Formate and igestymethyl tetramine on the undesirable, improperly fermented silage microflora is completely unexpected. As shown below, the comparative experiments using the proposed mixture achieve an excellent effect, which is superior to or at least equivalent to the effects of silage containing nitrite, but where the dangerous and undesirable nitrite is completely absent. If nitrite is added to the mixture of biocatalysts, in some cases it is possible to achieve a slight improvement in the effect of silage, but the use of nitrite also has the disadvantages described above. The synergism of the above-mentioned silage agents, depending on the concentration taken, is evident when studying the possibilities for the development of the most important pest, preventing its fermentation process - bacteria of the oil-acid fermentation type clostridium tyrobutyricum In the presence of one or several additives. The results of the experiments are given in table. one.
    Biocatalysts are taken in weight,% compared to the weight of the green feed of the silage product. The success of properly performed silage is determined by the amount of 60 nutrient loss that occurs when fermentation gas is formed as a result of enzymatic and microbiological nutrient splitting, 65 splitting protein measured by the content of NH in the silo and the content of siliceous butyric acid, determined by titration in accordance with the instructions of agricultural scientists Institutes, In Table. 2, these three criteria are used to determine the silage quality in comparative experiments with pasture grass.
    The fHj arising from NMT is retracted,
    As follows from this table, only a slight effect can be achieved with the help of individual components of the silage mixture.
    When formate is combined with NMT, the silage with low losses of fermentation gas is very good in quality, when, in a mixture with a very low NMT content, the proportion of formate is increased to such an extent that it constitutes 0.25% by weight in the silo. This positive effect from the combination of NMT with a high content of formate is also visible from the values of the table for the variant 0.25% formate and 0.025 NMT. The analytical values differ only slightly from the variant with doubled BWT content. From the point of view of the physiological acceptability of the finished silage, this fact is of great importance. It has recently been established that the total microbiological ottlement of formaldehyde in a silo: occurs when the initial content is at most 0.1 wt.%, And the flora natural for fermentation is not inhibited all the time (Beck and Gross, 1973),
    This confirms the results of microbiological studies, which resulted in an obvious positive synergistic effect on the fermentation process in the presence of a large amount of formate with a low content of BWM,
    The combination of formate and nitrate with a low content of formate has about the same effect as the corresponding combination with NMT, but with an increase in the content of formate, there is no further improvement. This means that with such a mixture, the effective component is practically exclusively nitTable2
    five
    rit, which also shows a comparison with .Na-nitrite as a separate substance.
    The mixture of biocatalysts proposed in the invention has a very important advantage, which consists in
    0 that it does not contain strong vegetable and nitrite.
    It is still unknown what the selective effect of formates and nitrite is based on.
    5 cells of silage microflora. Installed, It has been stated that during the fermentation process, due to the pH lowering, small amounts of formaldehyde are continuously split off from chestimetilovoy tetramine, a process occurs that is positively affected by the presence of formate. Similar eLFect can be achieved with the help of other biocatalysts,
    5 which, under the same conditions, slowly decompose the aldehyde. But from the point of view of profitability and safety, it is preferable to use a six-methyl tetra isomer.
    To improve the flowability and storage of the mixture, it can & be appropriate to add carriers to biocatalysts that do not adversely affect the silage product or improve its feed quality.
    5 These substances may also improve the use of silage. By using more added substances, a more even distribution of the strength of the product being produced, especially green plants, can be achieved, and the flowability of the silage means is also improved. Examples of carriers are ground raw phosphate, bone for feed meal,
    权利要求:
    Claims (1)
    [1]
    5 tricalyumphosphate, bolus, talc, alkaline earth stearate, common salt, salt and other minerals suitable for feeding with that. In application, the proposed siloing agent has good flowability and is easily dosed and can safely and cost effectively be used in operation, since, even a very small amount guarantees success, Formates, use in these concentrations as biological compounds, not from physiological point of view, six-methyl tetramine, added to the silage product at a concentration of up to 1.1%, is almost completely decomposed within a few weeks after the ammonium and formaldehyde have been thawed. Since nitrates are added to the product, they are present in such small quantities that they decompose within a few days before the fermentation begins. Example 1 When siloing 100 miles, 70 tons of alfalfa are added manually or continuously using a conventional metering device for bulk silage with 0.3% 210 kg of a mixture consisting of H5% Ca - formate and 15% six-methyl tetramine, In terms of O, 255% Ca-formate and 0.045% HMT were introduced in this way for the weight of green feed. Example 2 When ensiling with 200 m or 120 tons of grass, 0.2% 240 kg of a mixture consisting of 80% Ca - formate and 20% six-methyl tetramine are added continuously with a conventional dosing device. Thus, in terms of the weight of green feed, 0.16% Ca formate and 0.04% NMT were added, Example 3, When silage 400 m or 240 tons of silage maize is added continuously using a silo cutter or when filling the silo with the help of a conveyor or blower By means of a conventional dosing device, only 0.2% 480 kg of a mixture consisting of 60% Ca formate, 15% six-methyl tetramine and 25% crude phosphate as carrier. Thus, in terms of the weight of green fodder, 0.12% of Ca - formate and 0.03% of NMT are added. Claims An agent for plant silage, containing hexamethyltetramine and a bacteriostatic agent, which in order to increase its effectiveness as well as improve its physicomechanical properties, the agent contains calcium formate in the form of a bacteriostatic agent. weight,%: Hexamethyltetramine 10-50 Calcium formate 50-90 Sources of information taken into account in the examination 1, German Application No. 21589-16, Cl, A 23 K 3/00, 1972. 2, French Application No. 2225100, cl. A 23 K 3/00, 1974,
    类似技术:
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    EP0411827B1|1993-12-15|Ensiling composition
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    同族专利:
    公开号 | 公开日
    US4079150A|1978-03-14|
    FR2338654B1|1983-08-26|
    SE426542B|1983-01-31|
    DE2602626A1|1977-07-28|
    JPS5293577A|1977-08-06|
    DK27477A|1977-07-25|
    NO770202L|1977-07-26|
    NO141972C|1980-06-25|
    AT357017B|1980-06-10|
    DD127920A1|1977-10-19|
    BE850607A|1977-07-22|
    SE7700666L|1977-07-25|
    GB1557340A|1979-12-05|
    DK144932C|1983-01-24|
    FR2338654A1|1977-08-19|
    IT1074823B|1985-04-20|
    NO141972B|1980-03-03|
    DK144932B|1982-07-12|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    DE1217765B|1965-07-17|1966-05-26|Dr Carl Clemente|Silage additives and processes for their production|
    GB1432953A|1972-07-05|1976-04-22|Pan Britannica Ind Ltd|Preservation of silage|
    US3961079A|1972-11-24|1976-06-01|Plate Kofasil Gesellschaft Mit Beschrankter Haftung|Ensiling of green fodder with hexamethylene tetramine and sodium nitrite|FI63328C|1981-03-30|1983-06-10|Martti Emil Lampila|ENSILERINGMEDELKOMPOSITION FOER ENSILERING AV GROENFODER OCH LIKNANDE|
    DE3118918A1|1981-05-13|1982-12-02|Plate Bonn Gmbh, 5300 Bonn|SILICING AGENTS, THE USE THEREOF AND METHOD FOR IMPROVING THE FERMENTATION|
    US4772481A|1985-03-05|1988-09-20|Frontier Feeds, Inc.|Ruminant feed preservative compositions|
    DE3916563A1|1989-05-20|1990-11-22|Atochem Werke Gmbh|COMBINATION DEVICE AND METHOD FOR ACIDIFYING GREEN FORAGE AND PREVENTING AEROBIC DEGRADING PROCESSES IN GAERFUTTER|
    US10150612B2|2013-08-09|2018-12-11|Schlumberger Technology Corporation|System and method for delivery of oilfield materials|
    US10633174B2|2013-08-08|2020-04-28|Schlumberger Technology Corporation|Mobile oilfield materialtransfer unit|
    US20140041322A1|2012-08-13|2014-02-13|Schlumberger Technology Corporation|System and method for delivery of oilfield materials|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    DE19762602626|DE2602626A1|1976-01-24|1976-01-24|SILAGE COMPOUNDS FOR FORAGE PLANTS AND METHOD FOR THEIR ACIDIFICATION|
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